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• W2024423043 startingPage "1451" @default.
• W2024423043 abstract "In order to estimate online conversion and polymer composition through sound velocity measurements, a mathematical model for calculating sound velocity in emulsion polymerization has been developed. With respect to previous modeling approaches, its main features are as follows: (1) the application to three-phase, reacting systems of Urick equation (usually adopted for estimating sound velocity in multiphase, dispersed, unreacting systems, such as emulsions and suspensions); and (2) the development of an empirical relationship for estimating particle compressibility as a function of conversion during the reaction. The model has been validated through several sets of experimental data of batch and semibatch homo- and copolymerizations involving styrene, butyl acrylate, vinyl acetate, and methyl methacrylate. In most of the examined cases, the performances of the calibration model are satisfactory. © 1999 John Wiley & Sons, Inc. J Appl Polym Sci 72: 1451–1477, 1999" @default.
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• W2024423043 date "1999-06-13" @default.
• W2024423043 modified "2023-10-14" @default.
• W2024423043 title "Procedure for calibrating an ultrasonic sensor for online monitoring of conversion in latex reactors" @default.
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• W2024423043 doi "https://doi.org/10.1002/(sici)1097-4628(19990613)72:11<1451::aid-app8>3.0.co;2-6" @default.
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