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- W2024431696 startingPage "2341" @default.
- W2024431696 abstract "Single activities of the decyl sulfate (DeS−), the calcium (Ca2+), and the sodium (Na+) ions in mixed surfactant solutions of varying mole ratios (Rm=Ca(DeS)2/NaDeS) were obtained at 30±1 °C by means of three kinds of EMF cells with ion-exchange membranes or Na+-selective electrode. The results showed that with increasing concentrations above the cmc, the activity of the DeS− decreases gradually, while that of the Na+ increased linearly; the activity of the Ca2+ remained nearly constant in the solution of Rm=2, but it showed a minimum in the solutions of Rm=1, 0.5 and 0.2. From these activities, the counterion attachments of the Ca2+(rCa) and the Na+(rNa) and the degree of micellar charge (1−2rCa−rNa) were obtained. With increasing concentration, rCa diminished gradually and approached a constant value, while rNa and 1−2rCa−rNa changed reversely except in the solution of Rm=2 where they were nearly constant. The Ca2+ was bound preferentially to the micelle surface. The Na+, which almost diffused away for ..." @default.
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- W2024431696 date "1983-08-01" @default.
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- W2024431696 title "Ionic Composition of Micelles and the Dissolved State of the Mixed Surfactant Solutions of Calcium and Sodium Decyl Sulfates" @default.
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- W2024431696 doi "https://doi.org/10.1246/bcsj.56.2341" @default.
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