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• W2024444848 abstract "The first example of a non-enzymatic C-2 epimerization of aldonolactones is reported. The reaction of 2,3,4,6-tetra-O-benzyl-d-gluconolactone or 2,3,4,6-tetra-O-benzyl-d-mannonolactone with MgI2 in EtOH afforded their respective C-2 epimer. Studies conducted in EtOD showing the incorporation of a deuterium atom only at the C-2 position of the epimerized product reveal an epimerization rather than a racemization reaction. A mechanism involving a chelation with a magnesium species is proposed to explain this C-2 inversion reaction." @default.
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• W2024444848 date "2008-01-01" @default.
• W2024444848 modified "2023-10-12" @default.
• W2024444848 title "C-2 Epimerization of aldonolactones promoted by magnesium iodide: a new way towards non-enzymatic epimerization" @default.
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• W2024444848 doi "https://doi.org/10.1016/j.carres.2007.10.006" @default.
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