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- W2024446736 abstract "The rotational structure of a number of vibrational bands of keten has been analysed, and values have been derived for some of the rotational constants. Several parallel type bands give a value of Bo close to that obtained from the microwave spectrum (0.3371 cm−1). Two other bands, associated with stretching modes of the CCO chain, give values much higher than this. Examination of other published data on this molecule, and also of results on the related molecules diazomethane and allene-d2 suggest that a similar anomaly may occur in these cases. One perpendicular type band which is free from interactions has been analysed, and the value 9.34 cm−1 has been obtained for Ao. Using the measured values for Ao and Bo, the following geometrical parameters have been derived: r0CH = 1.075 Å, r0CO = 1.17 Å and ." @default.
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- W2024446736 date "1958-12-01" @default.
- W2024446736 modified "2023-09-25" @default.
- W2024446736 title "Vibration-rotation bands of keten" @default.
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