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- W2024451728 abstract "The sorption properties of synthetic zeolite omega have been studied using nitrogen, water, and hydrocarbons as sorbates. Samples were prepared from two parent materials appearing as hexagonal single crystals (0.7 × 2μm) or spherulitic aggregates of small particles (0.03 × 0.2 μm). The sorption characteristics of the hexagonal single crystals are fully consistent with the proposed framework structure. After exchange of the sodium and tetramethylammonium ions by protons their intracrystalline nitrogen and water pore volume corresponds to the calculated void space of the main channel, i.e., 0.09 ml g−1. Eighty-five and seventy percent of this volume are readily available to n-hexane and 1,3,5-trimethylbenzene, respectively. The polycrystalline spherulitic form of zeolite omega contains mesopores in addition to the micropores. The mesopores are able to sorb 1,3,5-triisopropylbenzene and may contribute to one-half of the sorption capacity determined at high relative pressure. The influence of the activation procedures on the porosity of zeolite omega is examined and it is suggested that the deactivation characteristics of the samples in the cracking of isooctane are related to diffusion kinetics." @default.
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- W2024451728 date "1988-05-01" @default.
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- W2024451728 title "Sorption properties of zeolite omega" @default.
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- W2024451728 doi "https://doi.org/10.1016/0021-9517(88)90069-3" @default.
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