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• W2024453513 abstract "Hydrolysis of scalemic trichloroacetamides Cl3CCONHCH(R)CHCH2 and allylation, or acylation with but-3-enoic acid, followed by ring-closing metathesis resulted in the formation of unsaturated pyrrolidine and piperidine building blocks. These were employed in the synthesis of (S)-coniine (R = Pr) and a formal synthesis of (+)-anisomycin (R = p-MeOC6H4). Extension of this methodology with R = CH2CHCH2 employing two ring-closing metatheses resulted in the synthesis of unsaturated quinolizidinone and indolizidinone frameworks." @default.
• W2024453513 created "2016-06-24" @default.
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• W2024453513 date "2009-05-29" @default.
• W2024453513 modified "2023-10-15" @default.
• W2024453513 title "Asymmetric Synthesis of Unsaturated Monocyclic and Bicyclic Nitrogen Heterocycles" @default.
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• W2024453513 doi "https://doi.org/10.1021/ol900880w" @default.
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