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• W2024457958 abstract "The structures of <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML id=M3><mml:mrow><mml:msub><mml:mrow><mml:mrow><mml:mo stretchy=false>[</mml:mo><mml:mrow><mml:msub><mml:mrow><mml:mrow><mml:mo stretchy=false>(</mml:mo><mml:mrow><mml:mtext>p</mml:mtext><mml:mtext>y</mml:mtext></mml:mrow><mml:mo stretchy=false>)</mml:mo></mml:mrow></mml:mrow><mml:mtext>2</mml:mtext></mml:msub><mml:mtext>C</mml:mtext><mml:mtext>d</mml:mtext><mml:mtext>F</mml:mtext><mml:mtext>e</mml:mtext><mml:msub><mml:mrow><mml:mrow><mml:mo stretchy=false>(</mml:mo><mml:mrow><mml:mtext>C</mml:mtext><mml:mtext>O</mml:mtext></mml:mrow><mml:mo stretchy=false>)</mml:mo></mml:mrow></mml:mrow><mml:mn>4</mml:mn></mml:msub></mml:mrow><mml:mo stretchy=false>]</mml:mo></mml:mrow></mml:mrow><mml:mn>3</mml:mn></mml:msub></mml:mrow></mml:math> and <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML id=M4><mml:mrow><mml:mrow><mml:mo stretchy=false>{</mml:mo><mml:mrow><mml:msub><mml:mrow><mml:mrow><mml:mo stretchy=false>(</mml:mo><mml:mrow><mml:mtext>T</mml:mtext><mml:mtext>H</mml:mtext><mml:mtext>F</mml:mtext></mml:mrow><mml:mo stretchy=false>)</mml:mo></mml:mrow></mml:mrow><mml:mtext>5</mml:mtext></mml:msub></mml:mrow></mml:mrow><mml:mrow><mml:mrow><mml:msub><mml:mrow><mml:mrow><mml:mo stretchy=false>[</mml:mo><mml:mrow><mml:mtext>C</mml:mtext><mml:mtext>d</mml:mtext><mml:mtext>F</mml:mtext><mml:mtext>e</mml:mtext><mml:msub><mml:mrow><mml:mrow><mml:mo stretchy=false>(</mml:mo><mml:mrow><mml:mtext>C</mml:mtext><mml:mtext>O</mml:mtext></mml:mrow><mml:mo stretchy=false>)</mml:mo></mml:mrow></mml:mrow><mml:mtext>4</mml:mtext></mml:msub></mml:mrow><mml:mo stretchy=false>]</mml:mo></mml:mrow></mml:mrow><mml:mtext>3</mml:mtext></mml:msub></mml:mrow><mml:mo stretchy=false>}</mml:mo></mml:mrow></mml:mrow></mml:math> have been determined (py = pyridine; THF = tetrahydrofuran). Each is composed of a six-membered ring having alternating cadmium and iron centers. The presence of the more strongly basic amine ligands in the former led to a greater contribution of an ionic resonance form, which resulted in overall longer Cd–Fe bonds and a greater contribution of a bicapped tetrahedral coordination geometry about iron. Thus, the Cd–Fe distances range from 2.5679(4) to 2.6501(1) Å for the THF complex versus 2.6445(8) to 2.6833(7) Å for the py complex. Similarly, the Fe–Cd–Fe and Cd–Fe–Cd angles for the THF complex fell in respective ranges of 139.03(2)–157.27(2)° and 84.41(1)–99.79(1)°, as compared to 135.31(3)–139.51(4)° and 102.52(3)–104.62(4)° for the py complex. The space group for the former compound is Pbcn , with <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML id=M5><mml:mrow><mml:mi>a</mml:mi></mml:mrow></mml:math> = 12.2678(2), <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML id=M6><mml:mrow><mml:mi>b</mml:mi></mml:mrow></mml:math> = 22.4601(5), and <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML id=M7><mml:mrow><mml:mi>c</mml:mi></mml:mrow></mml:math> = 17.0039(4) Å, while for the THF complex, the space group is <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML id=M8><mml:mrow><mml:mrow><mml:msub><mml:mrow><mml:mi>P</mml:mi><mml:mn>2</mml:mn></mml:mrow><mml:mrow><mml:mn>1</mml:mn></mml:mrow></mml:msub></mml:mrow><mml:mo>/</mml:mo><mml:mrow><mml:mi>c</mml:mi></mml:mrow></mml:mrow></mml:math>, with <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML id=M9><mml:mrow><mml:mi>a</mml:mi></mml:mrow></mml:math> = 10.7297(2), <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML id=M10><mml:mrow><mml:mi>b</mml:mi></mml:mrow></mml:math> = 20.4961(2), <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML id=M11><mml:mrow><mml:mi>c</mml:mi></mml:mrow></mml:math> = 18.7464(3) Å, and <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML id=M12><mml:mrow><mml:mi>β</mml:mi></mml:mrow></mml:math> = 94.2715(6)°." @default.
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• W2024457958 date "2014-02-13" @default.
• W2024457958 modified "2023-10-18" @default.
• W2024457958 title "Structural Studies of [(py)2CdFe(CO)4]3 and {(THF)5[CdFe(CO)4]3}" @default.
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• W2024457958 doi "https://doi.org/10.1155/2014/721978" @default.
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