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- W2024473400 abstract "Abstract A highly stereoselective Saucy–Marbet rearrangement using chiral ynamides and propargyl alcohols is described here. This rearrangement can be catalyzed by para-nitrobenzenesulfonic acid and leads to high diastereoselectivities for a range of different chiral propargyl alcohols and ynamides in a stereochemically intriguing matched, mismatched or indifferent manner. The stereoselective Saucy–Marbet rearrangement of ynamides provides an excellent entry to highly substituted chiral homo allenyl alcohols." @default.
- W2024473400 created "2016-06-24" @default.
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- W2024473400 date "2006-08-15" @default.
- W2024473400 modified "2023-09-23" @default.
- W2024473400 title "Synthesis of Chiral Allenes from Ynamides Through a Highly Stereoselective Saucy—Marbet Rearrangement." @default.
- W2024473400 cites W2953117064 @default.
- W2024473400 doi "https://doi.org/10.1002/chin.200633078" @default.
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