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- W2024490802 abstract "Abstract Trifluoroacetyl ethyl cellulose (TFAEC) was prepared by reaction of ethyl cellulose (EC) with trifluoroacetic anhydride. The effect of the trifluoroacetylation on the chain dynamics and thermal stability of the ethyl cellulose was investigated. Chain dynamics of TFAEC were investigated using the 1 H spin-lattice relaxation time in the rotating frame ( T H 1ρ ). The trifluoroacetylation reduced the mobility of the polymeric glucose chain. The apparent activation energies ( E a ) of degradation under nitrogen and air were evaluated by differential and integral methods. The value of E a of TFAEC under nitrogen was affected by the equivalent ratio of trifluoroacetic anhydride to EC, while that under air was less affected." @default.
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- W2024490802 date "2001-05-01" @default.
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- W2024490802 title "Chain dynamics and thermal stability of trifluoroacetylated ethyl cellulose" @default.
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- W2024490802 doi "https://doi.org/10.1016/s0141-3910(01)00021-0" @default.
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