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- W2024494078 abstract "Dinitrogen oxide was employed as a clean oxidant for various oxidations in the presence of a catalytic amount of dioxoruthenium tetramesitylporphyrin complex (Ru(tmp)(O)2). A variety of olefins, secondary alcohols, and benzyl alcohols were smoothly oxidized to the corresponding epoxides, ketones, and aldehydes in high yields. In the oxidation of 9,10-dihydroanthracene derivatives, the competitive reactions affording anthraquinones and anthracenes could be regulated by the reaction conditions. At a high temperature (200 °C), anthraquinones were selectively produced, while the anthracenes were selectively produced by the addition of sulfuric acid." @default.
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- W2024494078 date "2004-10-01" @default.
- W2024494078 modified "2023-10-03" @default.
- W2024494078 title "Nitrous Oxide Oxidation Catalyzed by Ruthenium Porphyrin Complex" @default.
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- W2024494078 doi "https://doi.org/10.1246/bcsj.77.1905" @default.
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