Matches in SemOpenAlex for { <https://semopenalex.org/work/W2024496438> ?p ?o ?g. }
- W2024496438 endingPage "8399" @default.
- W2024496438 startingPage "8399" @default.
- W2024496438 abstract "Cyclometalated aryl tetra- or trichlorido cyclopentadienyl tantalum complexes [TaXCl3{C6H4(2-CH2NMe2)-κ2C,N}] (X = Cl 1, η5-C5H52, η5-C5H4(SiMe3) 3, η5-C5Me54) containing a five-membered TaC3N chelate ring were synthesized by reaction of the TaXCl4 (X = Cl, η5-C5H5, η5-C5H4(SiMe3), η5-C5Me5) with the appropriate lithium aryl reagent [Li{C6H4(2-CH2NMe2)}]. The reported complexes were studied by IR and NMR spectroscopy and the X-ray molecular structures of compounds 2, 3 and 4 were determined by diffraction methods. These compounds were theoretically analyzed by the DFT method and their structures were rationalized. The preferential coordination of the 2-{(dimethylamino)methyl}phenyl ligand was justified by an analysis of the molecular orbitals of the Ta(η5-C5H5)Cl3 and C6H4(2-CH2NMe2) fragments. In addition, the exchange pathways that account for the NMR equivalency of the Me2N– methyl groups and –CH2– hydrogen atoms of the coordinated C6H4(2-CH2NMe2)-κ2C,N ligand were theoretically studied." @default.
- W2024496438 created "2016-06-24" @default.
- W2024496438 creator A5001488780 @default.
- W2024496438 creator A5013261333 @default.
- W2024496438 creator A5047142892 @default.
- W2024496438 creator A5066341327 @default.
- W2024496438 creator A5068101499 @default.
- W2024496438 creator A5080022184 @default.
- W2024496438 date "2011-01-01" @default.
- W2024496438 modified "2023-10-02" @default.
- W2024496438 title "Synthetic and structural studies of monocyclopentadienyl cyclometalated aryl tantalum(v) compounds" @default.
- W2024496438 cites W1507865272 @default.
- W2024496438 cites W1578050928 @default.
- W2024496438 cites W1966182479 @default.
- W2024496438 cites W1967976850 @default.
- W2024496438 cites W1968365423 @default.
- W2024496438 cites W1979721313 @default.
- W2024496438 cites W1988255155 @default.
- W2024496438 cites W1990719017 @default.
- W2024496438 cites W1992060262 @default.
- W2024496438 cites W1994332542 @default.
- W2024496438 cites W1998345643 @default.
- W2024496438 cites W2002788226 @default.
- W2024496438 cites W2004563571 @default.
- W2024496438 cites W2005110621 @default.
- W2024496438 cites W2007387460 @default.
- W2024496438 cites W2013628505 @default.
- W2024496438 cites W2021389295 @default.
- W2024496438 cites W2021880900 @default.
- W2024496438 cites W2023271753 @default.
- W2024496438 cites W2030151154 @default.
- W2024496438 cites W2041957473 @default.
- W2024496438 cites W2043242656 @default.
- W2024496438 cites W2054449133 @default.
- W2024496438 cites W2062514077 @default.
- W2024496438 cites W2063334178 @default.
- W2024496438 cites W2065117820 @default.
- W2024496438 cites W2065960157 @default.
- W2024496438 cites W2066771432 @default.
- W2024496438 cites W2078362677 @default.
- W2024496438 cites W2079347231 @default.
- W2024496438 cites W2086245238 @default.
- W2024496438 cites W2090867588 @default.
- W2024496438 cites W2095031597 @default.
- W2024496438 cites W2095274908 @default.
- W2024496438 cites W2097508262 @default.
- W2024496438 cites W2106912346 @default.
- W2024496438 cites W2143981217 @default.
- W2024496438 cites W2152033325 @default.
- W2024496438 cites W2154634991 @default.
- W2024496438 cites W2951413426 @default.
- W2024496438 cites W2953326530 @default.
- W2024496438 cites W87776471 @default.
- W2024496438 cites W2029420743 @default.
- W2024496438 doi "https://doi.org/10.1039/c1dt10223k" @default.
- W2024496438 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21779602" @default.
- W2024496438 hasPublicationYear "2011" @default.
- W2024496438 type Work @default.
- W2024496438 sameAs 2024496438 @default.
- W2024496438 citedByCount "2" @default.
- W2024496438 countsByYear W20244964382012 @default.
- W2024496438 countsByYear W20244964382022 @default.
- W2024496438 crossrefType "journal-article" @default.
- W2024496438 hasAuthorship W2024496438A5001488780 @default.
- W2024496438 hasAuthorship W2024496438A5013261333 @default.
- W2024496438 hasAuthorship W2024496438A5047142892 @default.
- W2024496438 hasAuthorship W2024496438A5066341327 @default.
- W2024496438 hasAuthorship W2024496438A5068101499 @default.
- W2024496438 hasAuthorship W2024496438A5080022184 @default.
- W2024496438 hasConcept C116569031 @default.
- W2024496438 hasConcept C134018914 @default.
- W2024496438 hasConcept C155647269 @default.
- W2024496438 hasConcept C161790260 @default.
- W2024496438 hasConcept C170493617 @default.
- W2024496438 hasConcept C178790620 @default.
- W2024496438 hasConcept C179104552 @default.
- W2024496438 hasConcept C181458950 @default.
- W2024496438 hasConcept C185592680 @default.
- W2024496438 hasConcept C197404232 @default.
- W2024496438 hasConcept C2778541603 @default.
- W2024496438 hasConcept C2780263894 @default.
- W2024496438 hasConcept C2780378348 @default.
- W2024496438 hasConcept C2781076698 @default.
- W2024496438 hasConcept C40875361 @default.
- W2024496438 hasConcept C514619126 @default.
- W2024496438 hasConcept C55493867 @default.
- W2024496438 hasConcept C66974803 @default.
- W2024496438 hasConcept C71240020 @default.
- W2024496438 hasConcept C71924100 @default.
- W2024496438 hasConcept C8010536 @default.
- W2024496438 hasConceptScore W2024496438C116569031 @default.
- W2024496438 hasConceptScore W2024496438C134018914 @default.
- W2024496438 hasConceptScore W2024496438C155647269 @default.
- W2024496438 hasConceptScore W2024496438C161790260 @default.
- W2024496438 hasConceptScore W2024496438C170493617 @default.
- W2024496438 hasConceptScore W2024496438C178790620 @default.
- W2024496438 hasConceptScore W2024496438C179104552 @default.
- W2024496438 hasConceptScore W2024496438C181458950 @default.