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- W2024497013 abstract "Abstract Sulfur dichloride diadducts of oleate esters, oleylnitrile, elaidate esters and ethyl linoleate were prepared by addition of the theoretical amount of sulfur dichloride to the fatty derivative. Similar diadducts were also prepared from commercial oleate esters including esters of ADM's monoenoic acid. Several of the resulting β,β' ‐dichlorosulfide diesters were then oxidized with peracetic acid to β,β' ‐dichlorosulfoxide diesters and to β,β' ‐dichlorosulfone diesters. The latter materials were converted to the divinyl sulfone diacids. Cis and trans‐2‐butene were used as model compounds for studying the addition of sulfur dichloride to oleates and elaidates respectively. The results on these systems, which paralleled the results with the fatty materials, indicated that substitution reactions were negligible and that the addition was stereoselective, that is, oleates and elaidates gave stereochemically different products." @default.
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- W2024497013 date "1967-10-01" @default.
- W2024497013 modified "2023-10-09" @default.
- W2024497013 title "Sulfur dichloride diadducts of unsaturated fatty derivatives. I. preparation and oxidation" @default.
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- W2024497013 doi "https://doi.org/10.1007/bf02901250" @default.
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