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- W2024508965 abstract "Crosslinkable ruthenium complex dye, Ru(2,2′-bipyridine-4,4′-bicarboxylic acid)(4,4′-bis((4-vinyl benzyloxy)methyl)-2,2′-bipyridine)(NCS)2 (denoted as Ru-S dye), was synthesized and characterized using 1H-NMR, 13C-NMR, Fourier transform infrared (FTIR) and UV/vis spectroscopies.The power conversion efficiency of dye-sentitized solar cell (DSSC) using Ru-S and liquid electrolyte containing lithium iodide (LiI) reached 7.53% under standard global AM 1.5 full sunlight, which is partly attributed to Li+ being coordinated by Ru-S as verified by ATR-FTIR spectroscopy. As Ru-S was further crosslinked with glycerol propoxylate triacrylate (GPTA), not only 89% of dye retained on TiO2 mesoporous surface after rinsed by 0.1 N NaOH aqueous solution, the power efficiency was also increased to 7.88%. As poly(methyl acrylate) was used to gel the electrolyte system, the power efficiency of DSSC with Ru-S dye was 6.96% but increased to 7.57% after crosslinking with GPTA. Notably, both DSSCs showed a good long-term stability after one month storage." @default.
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- W2024508965 date "2011-07-01" @default.
- W2024508965 modified "2023-10-17" @default.
- W2024508965 title "Synthesis and characterization of cross-linkable ruthenium dye with ion coordinating property for dye-sensitized solar cells" @default.
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- W2024508965 doi "https://doi.org/10.1016/j.polymer.2011.05.035" @default.
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