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- W2024525059 abstract "Intermediates formed during radioylsis of benzyl alcohol have been identified by an e.s.r. and spin trapping method. Solutions of tert-BuNO in benzyl alcohol were irradiated insitu with 3 MeV electrons and the e.s.r. spectra of the resulting nitroxides directly recorded.[Formula: see text]These demonstrated that benzyl, PhCH 2 .,and hydroxybenzyl, PhĊHOH, radicals are formed in the radiolysis. By an examination of the effects of the addition of electron scavengers, it was shown that the benzyl radicals are probably directly formed from the reaction of electrons with benzyl alcohol. Since these scavengers had no effect on the yield of PhĊHOH trapped, this radical is not derived from the reactions of electrons. It is suggested that it is partly produced by reaction of the alkoxy radical, PhCH 2 O.,with the solvent benzyl alcohol.[Formula: see text]" @default.
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- W2024525059 date "1975-10-15" @default.
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- W2024525059 title "Direct Observation of the Radicals Formed in the Radiolysis of Liquid Benzyl Alcohol. An Electron Spin Resonance and Spin Trapping Method" @default.
- W2024525059 doi "https://doi.org/10.1139/v75-444" @default.
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