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- W2024545125 abstract "Depending on the steric hindrance of the reaction centers, hemiacetal vinylogs 1 in the presence of BF3.OEt2 can, with enol ethers, lead to a Michael-type addition (4) or an aldolisation-type reaction (3). Hemiacetal vinylog 1b always yields the second reaction leading to β-methoxy-γ,δ-ethylenic carbonyl compounds 4 precursors of polyenic carbonyl compounds 5. Crotonaldehyde and methanol can be used instead of compound 1b." @default.
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- W2024545125 date "1993-06-01" @default.
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- W2024545125 title "Aldolisation-type reaction versus Michael-type addition. Hemiacetal vinylogs: Versatile synthons." @default.
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- W2024545125 doi "https://doi.org/10.1016/s0040-4039(00)60526-9" @default.
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