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• W2024558989 abstract "We have fabricated new types of polymer hydrogels and polymer nanocomposites, that is, nanocomposite gels (NC gels) and soft polymer nanocomposites (M-NCs), with novel organic/inorganic network structures. Both NC gels and M-NCs were synthesized by in situ free-radical polymerization in the presence of exfoliated clay platelets in aqueous systems and were obtained in various forms and sizes with a wide range of clay contents. Here, disk-like inorganic clay nanoparticles function as multifunctional crosslinkers to form new types of network systems. NC gels have extraordinary optical, mechanical and swelling/deswelling properties, as well as a number of new characteristics relating to optical anisotropy, polymer/clay morphology, biocompatibility, stimuli-sensitive surfaces, micropatterning and so on. The M-NCs also exhibit dramatic improvements in optical and mechanical properties including ultrahigh reversible extensibility and well-defined yielding behavior, despite their high clay contents. Thus, the serious disadvantages (intractability, mechanical fragility, optical turbidity, poor processing ability, low stimulus sensitivity and so on) associated with the conventional, chemically crosslinked polymeric materials were overcome in NC gels and M-NCs. New types of polymer hydrogels (nanocomposite gels, NC gels) and soft polymer nanocomposites (M-NCs) with novel organic/inorganic network structures were synthesized using disk-like inorganic clay nanoparticles as multifunctional crosslinkers to form new network systems. Both NC gels and M-NCs have extraordinary optical and mechanical properties, such as ultrahigh reversible extensibility, as well as a number of new characteristics relating to polymer/clay morphology, stimulus-sensitivity, biocompatibility, surface properties, micropatterning and so on. The serious disadvantages (intractability, mechanical fragility, optical turbidity, poor processing ability, low stimulus sensitivity) associated with the conventional, chemically crosslinked polymeric materials were overcome in NC gels and M-NCs." @default.
• W2024558989 created "2016-06-24" @default.
• W2024558989 creator A5018220902 @default.
• W2024558989 date "2011-01-19" @default.
• W2024558989 modified "2023-10-11" @default.
• W2024558989 title "Synthesis and properties of soft nanocomposite materials with novel organic/inorganic network structures" @default.
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• W2024558989 doi "https://doi.org/10.1038/pj.2010.141" @default.
• W2024558989 hasPublicationYear "2011" @default.
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