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• W2024562516 abstract "From an infrared study of gaseous TiF2 and TiF3 species isolated in neon and argon rare-gas matrices values of the symmetric and antisymmetric vibrational frequencies were obtained. Bond-angle measurements for TiF2, made using the isotope shift method, indicated a value of 130° ± 5°. This result has been rationalized in terms of possible electronic configurations for TiF2. Equilibrium constants for the reaction 2TiF3(g)+Ti(s)→3TiF2(g) were measured and combined with calculated free-energy-function data to indicate the stability of TiF2." @default.
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• W2024562516 date "1969-09-15" @default.
• W2024562516 modified "2023-10-14" @default.
• W2024562516 title "Infrared Spectra and Geometry of TiF₂ and TiF₃ in Rare‐Gas Matrices" @default.
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• W2024562516 doi "https://doi.org/10.1063/1.1672391" @default.
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