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• W2024563104 abstract "Self-assembled monolayers (SAMs) of n-octadecanethiol, n-dodecanethiol and n-pentanethiol formed by contact printing and solution adsorption are characterized by electrochemical impedance spectroscopy (EIS). Impedance measurements show that monolayers prepared by contact printing are on the order of 5 times less resistive to charge transfer and have greater defect density than monolayers prepared by solution adsorption. Modeling of the average defect size and density show that the size of monolayer defects stays relatively constant independent of the monolayer preparation conditions; however, the density of defects decreases with increasing concentration for the contact printed monolayers. The impedance data also show that monolayers prepared by solution adsorption have fewer defects than those prepared by contact printing." @default.
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• W2024563104 date "2009-08-01" @default.
• W2024563104 modified "2023-09-26" @default.
• W2024563104 title "Impedance differences found with n-alkanethiol monolayers prepared by contact printing and solution adsorption" @default.
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• W2024563104 doi "https://doi.org/10.1016/j.jcis.2009.04.051" @default.
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