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- W2024570066 abstract "The biosynthetic origin of the botcinolide skeleton was investigated by means of feeding 13C- and 2H-labeled precursors to Botrytis cinerea. Three new compounds, two homobotcinolide derivatives, 3-O-acetylhomobotcinolide (5) and 8-methylhomobotcinolide (6), and a new 11-membered lactone (7), were isolated. Their structures were elucidated on the basis of spectroscopic data, including one-bond and long-range 1H−13C correlations. The relative stereochemistries were determined by combined analyses of NOE data and 1H−1H coupling constants. According to the results of feeding experiments with 13C- and 2H-labeled acetate and l-S-methylmethionine, 5 is an acetate-derived polyketide whose methyl groups originate from l-S-methylmethionine. This is a rare example of the incorporation of a methyl from methionine into a supposed C3 starter unit of the polyketide synthesis." @default.
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- W2024570066 date "2005-12-15" @default.
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- W2024570066 title "Biosynthetic Studies on the Botcinolide Skeleton: New Hydroxylated Lactones from <i>Botrytis </i><i>c</i><i>inerea</i>" @default.
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- W2024570066 doi "https://doi.org/10.1021/jo051993s" @default.
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