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• W2024571427 abstract "Abstract The results of optical studies of Eu 3+ ions doped nanocrystalline materials which undergo structural phase transitions: SrTiO 3 :Eu 3+ and BaTiO 3 :Eu 3+ are presented. Nanocrystalline SrTiO 3 and BaTiO 3 samples with crystallite sizes about 25–50 nm were produced by the sol‐gel process. The Eu 3+ 5 D 0,1 → 7 F n fluorescence spectra were studied. Time‐resolved fluorescence spectra enabled to separate different kinds of Eu 3+ centers in BaTiO 3 samples. Fluorescence spectroscopy of probe Eu 3+ ions was used to detect the structural O h – D 4h phase transition in nanocrystalline SrTiO 3 . The Eu 3+ excited states lifetimes were studied in a wide temperature range and the effects of modified refractive index of the media on radiative transitions were observed. The study of ferroelectric C 4v – O h phase transition in nanocrystalline BaTiO 3 with optical second harmonic generation technique revealed remarkable hysteresis in the temperature dependence of the second harmonic intensity. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)" @default.
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• W2024571427 date "2007-03-01" @default.
• W2024571427 modified "2023-10-18" @default.
• W2024571427 title "Nanocrystalline SrTiO₃:Eu³⁺ and BaTiO₃:Eu³⁺: fluorescence spectroscopy and optical studies of structural phase transitions" @default.
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• W2024571427 doi "https://doi.org/10.1002/pssc.200673787" @default.
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