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- W2024578050 abstract "Scutegalin B (4), a natural neoclerodane diterpenoid possessing phagostimulant activity against larvae of the lepidopteran Spodoptera littoralis, has been subjected to a series of chemical transformations obtaining several derivatives. The activity of some of these changes to antifeedant (10, 12, 16, and 17), although other derivatives are inactive (6, 7, and 15) or maintain phagostimulant activity (8 and 9) of the starting material (4). The most potent antifeedant was 16, which possesses 16,15-lactone and a (19S)-19,2α-hemiacetal groups instead of the 16,15-lactol and (19R)-(19-O-tigloyl)19,2α-hemiacetal of the phagostimulant precursor 4. These and other structure−activity relationships are discussed, establishing that the biological action is strongly modulated by minimal structural variations." @default.
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- W2024578050 date "1999-04-01" @default.
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- W2024578050 title "From a Phagostimulant Natural Product to Semisynthetic Antifeedants Against <i>Spodoptera </i><i>l</i><i>ittoralis</i> Larvae: Chemical Transformations of the Neoclerodane Diterpenoid Scutegalin B" @default.
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- W2024578050 doi "https://doi.org/10.1021/np9805286" @default.
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