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• W2024580904 abstract "[BDTA]2[Cu(mnt)2] (BDTA = benzo-1,3,2-dithiazolyl, mnt = maleonitriledithiolate) was crystallized in the space group P with an inversion center on Cu giving a stacked structure with each metal complex anion sandwiched by two cations. Short intermolecular S...S contacts give rise to a one-dimensional chain lateral to the stacking axis. Variable-temperature magnetic susceptibility and EPR measurements indicate that the salt behaves as an ideal one-dimensional Heisenberg antiferromagnetic material from 2 K < or = T < or = 300 K, with a coupling constant of J/k(B) = 16-17 K; the very low temperature magnetic properties are in quantitative agreement with the predictions of quantum field theory. DFT calculations are consistent with the formation of a one-dimensional magnetic chain with interstack interactions mediated by the BDTA counterions." @default.
• W2024580904 created "2016-06-24" @default.
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• W2024580904 date "2005-01-13" @default.
• W2024580904 modified "2023-10-17" @default.
• W2024580904 title "[BDTA]₂[Cu(mnt)₂]: An Almost Perfect One-Dimensional Magnetic Material" @default.
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• W2024580904 doi "https://doi.org/10.1021/ic048479+" @default.
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