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- W2024582655 abstract "The reaction of 2-amino-2-deoxy-d-glycero-d-altro-heptose hydrochloride with acyclic and cyclic 1,3-dicarbonyl compounds gives, respectively, (d-allo-pentitol-1-yl)-pyrroles and -tetrahydroindoles that can be dehydrated to yield d-ribo-C-glycosyl heterocycles having furanoid or pyranoid structures, depending on the reaction conditions. Thus, when the reactions were kinetically controlled, α- and β-d-ribofuranosyl heterocycles were obtained, but α- and β-d-ribopyranosyl heterocycles were formed under conditions of thermodynamic control. A criterion is proposed to differentiate between both structures on the basis of the mass spectra of their triacetates." @default.
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- W2024582655 date "1985-11-01" @default.
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- W2024582655 title "Synthesis of d-ribo-C-nucleoside analogues by dehydration of new d-allo-pentitol-1-yl heterocycles" @default.
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