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• W2024583000 abstract "first_page settings Order Article Reprints Font Type: Arial Georgia Verdana Font Size: Aa Aa Aa Line Spacing:    Column Width:    Background: Open AccessCommentary Comments on “K. L. Cheng, Capacitor Theory for Nonfaradaic Potentiometry. Microchemical Journal 1990, 42, 524” and Reply to “Comments on ‘E. Pungor, The New Theory of Ion Selective Electrodes. Sensors 2001, 1, 1-12’ ” by Ernõ Pungor Institute for General and Analytical Chemistry, Budapest University of Technology and Economics, H-1111 Budapest, Gellért tér 4. Hungary. Sensors 2004, 4(1), 16-17; https://doi.org/10.3390/s40100016 Received: 22 March 2004 / Accepted: 23 March 2004 / Published: 30 March 2004 Download Download PDF Download PDF with Cover Download XML Download Epub Versions Notes I have sent the cited article [1] to the Sensors as a summing contribution, to inform those working in the field of ISE about my results coming from approximately 30 years of research activity. Thus far I used to send detailed publications to newspapers with a wider range of interests. At the time when I was publishing the first ion-selective electrode outside of glass-electrode [2], it was a general opinion that ions diffuse through the membrane.This was contradicted by the first response-time measurements, which were later further strengthened [3,4].Conversely to the many times published response-time measurements, we did not use the response-time measurement of electrochemical cells, but the reaction occurring on the measuring electrode. The response-time of the later system is about 20-40 milliseconds. Further investigations certified that the potential-signal appeared only by the surface reactions [5,6]. The question of the surface reaction was confirmed by glass-electrodes as well [7].In the published article [1] the phenomena were explained through a chemical approach. Cheng's approach [8] is very good; he used a physical model for this. These two do not oppose to each other. We had published already in the 80's that the potential is defined by the surface reactions. The acceptation of this idea has been accepted in the literature as well.Figures, analogue to that adopted from Professor Buck were already published long before in the papers of Simon [9] and his colleges in 1972, and therefore I did not think, any rights would valid to this. References and NotePungor, E. The New Theory of Ion Selective Electrodes. Sensors 2001, 1, 1–12. [Google Scholar]Pungor, E.; Hollós-Rokosinyi, E. Acta Chem. Hung 1961, 27, 63.Tóth, K.; Gavallér, I.; Pungor, E. Anal. Chem. Acta 1971, 57, 131.Lindner, E.; Tóth, K.; Pungor, E. Anal. Chem. 1976, 48, 1071.Lindner, E.; Tóth, K.; Pungor, E. Anal. Chem. 1992, 54, 1094.Lindner, E.; Tóth, K.; Pungor, E. Anal. Chem. 1984, 55, 808.Pungor, E. Microchem. J. 1997, 57, 251.Cheng, K.L. Capacitor theory for nonfaradaic potentiometry. Microchem. J. 1990, 42, 524. [Google Scholar]See: Simon, W.; Morf, W. E. Symp. Mátrafüred 1972, p. 127., figure. © 2004 by MDPI ( http://www.mdpi.org). Reproduction is permitted for noncommercial purposes. Share and Cite MDPI and ACS Style Pungor, E. Comments on “K. L. Cheng, Capacitor Theory for Nonfaradaic Potentiometry. Microchemical Journal 1990, 42, 524” and Reply to “Comments on ‘E. Pungor, The New Theory of Ion Selective Electrodes. Sensors 2001, 1, 1-12’ ”. Sensors 2004, 4, 16-17. https://doi.org/10.3390/s40100016 AMA Style Pungor E. Comments on “K. L. Cheng, Capacitor Theory for Nonfaradaic Potentiometry. Microchemical Journal 1990, 42, 524” and Reply to “Comments on ‘E. Pungor, The New Theory of Ion Selective Electrodes. Sensors 2001, 1, 1-12’ ”. Sensors. 2004; 4(1):16-17. https://doi.org/10.3390/s40100016 Chicago/Turabian Style Pungor, Ernõ. 2004. Comments on “K. L. Cheng, Capacitor Theory for Nonfaradaic Potentiometry. Microchemical Journal 1990, 42, 524” and Reply to “Comments on ‘E. Pungor, The New Theory of Ion Selective Electrodes. Sensors 2001, 1, 1-12’ ” Sensors 4, no. 1: 16-17. https://doi.org/10.3390/s40100016 Find Other Styles Article Metrics No No Article Access Statistics For more information on the journal statistics, click here. Multiple requests from the same IP address are counted as one view." @default.
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