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• W2024584770 startingPage "136" @default.
• W2024584770 abstract "Layered double hydroxides (LDHs) reactivity and interfacial behavior are closely interconnected and control particle properties relevant to the wide range of these solids’ applications. Despite their importance, their relationship has been hardly described. In this work, chloride and dodecylsulfate (DDS−) intercalated LDHs are studied combining experimental data (electrophoretic mobility and contact angle measurements, hydroxyl and organic compounds uptake) and a simple mathematical model that includes anion-binding and acid–base reactions. This approach evidences the anion effect on LDHs interfacial behavior, reflected in the opposite particle charge and the different surface hydrophobic/hydrophilic character. LDHs reactivity are also determined by the interlayer composition, as demonstrated by the cation uptake capability of the DDS− intercalated sample. Consequently, the interlayer anion modifies the LDHs interfacial properties and reactivity, which in turn extends the customization capacity of these solids." @default.
• W2024584770 created "2016-06-24" @default.
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• W2024584770 creator A5027052157 @default.
• W2024584770 creator A5050924021 @default.
• W2024584770 creator A5076296089 @default.
• W2024584770 date "2011-07-01" @default.
• W2024584770 modified "2023-10-01" @default.
• W2024584770 title "The effect of interlayer anion on the reactivity of Mg–Al layered double hydroxides: Improving and extending the customization capacity of anionic clays" @default.
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• W2024584770 doi "https://doi.org/10.1016/j.jcis.2011.03.056" @default.
• W2024584770 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21501846" @default.
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