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- W2024587093 abstract "[reaction: see text]A need to prepare large quantities of phenylisoserine for the semisynthesis of paclitaxel prompted us to examine the Sharpless amidohydroxylation reaction to see if it could be run at concentrations greater than those reported in the literature. During these investigations, we discovered that the amount of amidoalcohol produced in the reaction decreased while the diol side product increased as the concentration increased. We discovered that acetamide suppresses this side reaction and allows us to run the chemistry at 0.1 g/mL rather than the 0.014 g/mL reported in the literature." @default.
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- W2024587093 date "2000-07-25" @default.
- W2024587093 modified "2023-10-09" @default.
- W2024587093 title "Concentration Dependence of the Sharpless Asymmetric Amidohydroxylation of Isopropyl Cinnamate" @default.
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- W2024587093 doi "https://doi.org/10.1021/ol006198+" @default.
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