Matches in SemOpenAlex for { <https://semopenalex.org/work/W2024593227> ?p ?o ?g. }
- W2024593227 endingPage "8324" @default.
- W2024593227 startingPage "8319" @default.
- W2024593227 abstract "The electrochemical behavior of tris(4-bromophenyl)amine (TBPA) and 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) was comparatively studied in room temperature ionic liquids (RTILs) containing 1-butyl-3-methylimidazolium cation [BMIm]+ and the anions BF4−, PF6−and CF3SO3−. TEMPO showed a well-defined electrochemical reversibility with anodic to cathodic peak current ratio (Ia/Ic) equals to unity in all RTILs, at a glassy carbon electrode. In contrast, Ia/Ic ratio greater than unity was observed at all scan rates employed (10–1000 mV s−1) in cyclic voltammograms (CV) of TBPA in RTILs. Controlled-potential bulk electrolysis of TBPA in RTILs yielded a dark blue colored solution of monocation TBPA+, which is stable under nitrogen. Diffusion coefficient of TBPA+ cation was determined in all three ILs by chronoamperometry and found to be at least one order of magnitude less than the calculated value of TBPA. This effect, in conjunction with the deviation of the Ia/Ic ratio from unity could be ascribed to ion-pairing interaction between the TBPA+ cation and the anion of the RTILs." @default.
- W2024593227 created "2016-06-24" @default.
- W2024593227 creator A5057428307 @default.
- W2024593227 creator A5061361365 @default.
- W2024593227 date "2010-11-01" @default.
- W2024593227 modified "2023-10-18" @default.
- W2024593227 title "Electrochemical study of tris(4-bromophenyl)amine and 2,2,6,6-tetramethylpiperidine-1-oxyl in room-temperature ionic liquids" @default.
- W2024593227 cites W1963739212 @default.
- W2024593227 cites W1964776246 @default.
- W2024593227 cites W1966886172 @default.
- W2024593227 cites W1967562361 @default.
- W2024593227 cites W1967727210 @default.
- W2024593227 cites W1978473365 @default.
- W2024593227 cites W1980278031 @default.
- W2024593227 cites W1986773705 @default.
- W2024593227 cites W1990279333 @default.
- W2024593227 cites W1992236000 @default.
- W2024593227 cites W1993992414 @default.
- W2024593227 cites W1994341063 @default.
- W2024593227 cites W2000896609 @default.
- W2024593227 cites W2001435566 @default.
- W2024593227 cites W2005240065 @default.
- W2024593227 cites W2013070748 @default.
- W2024593227 cites W2018833705 @default.
- W2024593227 cites W2021219814 @default.
- W2024593227 cites W2027206984 @default.
- W2024593227 cites W2028737401 @default.
- W2024593227 cites W2039166697 @default.
- W2024593227 cites W2040580919 @default.
- W2024593227 cites W2048578974 @default.
- W2024593227 cites W2049807213 @default.
- W2024593227 cites W2051025840 @default.
- W2024593227 cites W2052126146 @default.
- W2024593227 cites W2062932961 @default.
- W2024593227 cites W2064269661 @default.
- W2024593227 cites W2067410595 @default.
- W2024593227 cites W2083205951 @default.
- W2024593227 cites W2084992947 @default.
- W2024593227 cites W2086713708 @default.
- W2024593227 cites W2107105885 @default.
- W2024593227 cites W2158042412 @default.
- W2024593227 cites W2168743201 @default.
- W2024593227 cites W2169950606 @default.
- W2024593227 cites W4248104288 @default.
- W2024593227 doi "https://doi.org/10.1016/j.electacta.2010.04.048" @default.
- W2024593227 hasPublicationYear "2010" @default.
- W2024593227 type Work @default.
- W2024593227 sameAs 2024593227 @default.
- W2024593227 citedByCount "5" @default.
- W2024593227 countsByYear W20245932272015 @default.
- W2024593227 countsByYear W20245932272016 @default.
- W2024593227 countsByYear W20245932272017 @default.
- W2024593227 countsByYear W20245932272020 @default.
- W2024593227 crossrefType "journal-article" @default.
- W2024593227 hasAuthorship W2024593227A5057428307 @default.
- W2024593227 hasAuthorship W2024593227A5061361365 @default.
- W2024593227 hasConcept C113196181 @default.
- W2024593227 hasConcept C131779359 @default.
- W2024593227 hasConcept C145148216 @default.
- W2024593227 hasConcept C147789679 @default.
- W2024593227 hasConcept C154881586 @default.
- W2024593227 hasConcept C161790260 @default.
- W2024593227 hasConcept C17525397 @default.
- W2024593227 hasConcept C178790620 @default.
- W2024593227 hasConcept C179104552 @default.
- W2024593227 hasConcept C185592680 @default.
- W2024593227 hasConcept C2776422427 @default.
- W2024593227 hasConcept C2777869211 @default.
- W2024593227 hasConcept C2778141235 @default.
- W2024593227 hasConcept C52859227 @default.
- W2024593227 hasConceptScore W2024593227C113196181 @default.
- W2024593227 hasConceptScore W2024593227C131779359 @default.
- W2024593227 hasConceptScore W2024593227C145148216 @default.
- W2024593227 hasConceptScore W2024593227C147789679 @default.
- W2024593227 hasConceptScore W2024593227C154881586 @default.
- W2024593227 hasConceptScore W2024593227C161790260 @default.
- W2024593227 hasConceptScore W2024593227C17525397 @default.
- W2024593227 hasConceptScore W2024593227C178790620 @default.
- W2024593227 hasConceptScore W2024593227C179104552 @default.
- W2024593227 hasConceptScore W2024593227C185592680 @default.
- W2024593227 hasConceptScore W2024593227C2776422427 @default.
- W2024593227 hasConceptScore W2024593227C2777869211 @default.
- W2024593227 hasConceptScore W2024593227C2778141235 @default.
- W2024593227 hasConceptScore W2024593227C52859227 @default.
- W2024593227 hasIssue "27" @default.
- W2024593227 hasLocation W20245932271 @default.
- W2024593227 hasOpenAccess W2024593227 @default.
- W2024593227 hasPrimaryLocation W20245932271 @default.
- W2024593227 hasRelatedWork W1967383804 @default.
- W2024593227 hasRelatedWork W1992446052 @default.
- W2024593227 hasRelatedWork W2000169131 @default.
- W2024593227 hasRelatedWork W2006292130 @default.
- W2024593227 hasRelatedWork W2074103703 @default.
- W2024593227 hasRelatedWork W2085228551 @default.
- W2024593227 hasRelatedWork W2109561131 @default.
- W2024593227 hasRelatedWork W2116860354 @default.
- W2024593227 hasRelatedWork W2161262616 @default.
- W2024593227 hasRelatedWork W2514429657 @default.