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- W2024609474 abstract "Excess volumes measured at 298.15 K in a successive-dilution dilatometer are reported for binary mixtures of (2-methylbutan-2-ol + n-heptane) and of (cyclopentanol + n-heptane). The 2-methylbutan-2-ol mixture exhibits positive excess volumes over the whole mole-fraction range. In contrast to this behavior, the excess volumes of the cyclopentanol mixture show a sigmoid dependence on composition, with positive values limited to lower mole fractions of alkanol than observed previously for (pentan-1-ol + n-heptane). Excess partial molar volumes of the components were calculated for both mixtures, and their values at infinite dilution were estimated. The excess volumes of these mixtures are attributed to a balance between H-bonding, non-specific interactions, and structural effects." @default.
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- W2024609474 title "Excess volumes for (2-methylbutan-2-ol + n-heptane) and for (cyclopentanol + n-heptane)" @default.
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- W2024609474 doi "https://doi.org/10.1016/0021-9614(85)90064-3" @default.
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