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- W2024615050 abstract "A new strategy to prepare pyrophosphate analogues through selective and quantitative cleavage of N-(O-alkylsulfamoyl)trialkylphospha-λ5-azene esters (R–O–SO2–NP(OR′)3) has been developed. Using pure bromotrimethylsilane, N-(O-alkyl-sulfamoyl)tristrimethylsilylphospha-λ5-azenes (R–O–SO2–NP(OSiMe3)3) have been easily obtained as intermediates. N-(O-Alkyl-sulfamoyl)phosphoramidic acids (R–O–SO2–NH–P(O)(OH)2) have been formed quantitatively by hydrolysis of the silylated intermediates." @default.
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- W2024615050 date "2004-03-01" @default.
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- W2024615050 title "New pyrophosphate analogues: a facile access to N-(O-alkyl-sulfamoyl)phosphoramidic acids via a simple and quantitative reaction of N-(O-alkylsulfamoyl)trimethylphospha-λ5-azene with bromotrimethylsilane and water" @default.
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- W2024615050 doi "https://doi.org/10.1016/j.tet.2004.01.035" @default.
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