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- W2024622527 abstract "Observation, investigation, and characterization of vacuum ultraviolet (VUV) $(ensuremath{sim}10phantom{rule{0.3em}{0ex}}mathrm{eV})$ luminescence due to interconfigurational $4{f}^{nensuremath{-}1}5dtext{ensuremath{-}}4{f}^{n}$ transitions in ${mathrm{Gd}}^{3+}$ and ${mathrm{Lu}}^{3+}$ are reported. High-resolution $(ensuremath{sim}0.5phantom{rule{0.3em}{0ex}}mathrm{AA{}})$ VUV emission and excitation spectra as well as decay kinetics of VUV luminescence have been measured for $mathrm{Li}mathrm{Gd}{mathrm{F}}_{4}$, $mathrm{Gd}{mathrm{F}}_{3}$, $mathrm{Li}mathrm{Lu}{mathrm{F}}_{4}$, and $mathrm{Lu}{mathrm{F}}_{3}$ crystals using synchrotron radiation. The obtained results are the direct proof that the VUV luminescence observed from $mathrm{Li}mathrm{Gd}{mathrm{F}}_{4}$ or $mathrm{Gd}{mathrm{F}}_{3}$ crystals and $mathrm{Li}mathrm{Lu}{mathrm{F}}_{4}$ or $mathrm{Lu}{mathrm{F}}_{3}$ originates from $4{f}^{6}5dtext{ensuremath{-}}4{f}^{7}$ transitions in ${mathrm{Gd}}^{3+}$ and $4{f}^{13}5dtext{ensuremath{-}}4{f}^{14}$ transitions in ${mathrm{Lu}}^{3+}$, respectively. The fine structure due to zero-phonon and vibronic lines was well resolved in VUV emission and excitation spectra of $mathrm{Li}mathrm{Gd}{mathrm{F}}_{4}$, whereas the spectra of $mathrm{Gd}{mathrm{F}}_{3}$ and $mathrm{Lu}{mathrm{F}}_{3}$ have a smooth shape because of stronger electron-lattice coupling between the $4{f}^{nensuremath{-}1}5d$ electronic configuration of the ${mathrm{Gd}}^{3+}$ and ${mathrm{Lu}}^{3+}$ ions and the lattice vibrations." @default.
- W2024622527 created "2016-06-24" @default.
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- W2024622527 date "2004-12-03" @default.
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- W2024622527 title "High-resolution vacuum ultraviolet spectroscopy of<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:mn>5</mml:mn><mml:mi>d</mml:mi><mml:mtext>−</mml:mtext><mml:mn>4</mml:mn><mml:mi>f</mml:mi></mml:mrow></mml:math>transitions in Gd and Lu fluorides" @default.
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- W2024622527 doi "https://doi.org/10.1103/physrevb.70.241101" @default.
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