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- W2024632595 abstract "Abstract The following reactions 2 Zn ( Ac ) 2 ·2 H 2 O ( s )+ H 5 IO 6 ( s )→ Zn 2 HIO 6 ·1.25 H 2 O ( s )+4 HAc ( l )+2.75 H 2 O ( l ) 2 Cd ( Ac ) 2 ·2 H 2 O ( s )+ H 5 IO 6 ( s )→ Cd 2 HIO 6 ·1.25 H 2 O ( s )+4 HAc ( l )+1.25 H 2 O ( l ) 2 Cu ( Ac ) 2 · H 2 O ( s )+ H 5 IO 6 ( s )→ Cu 2 HIO 6 ·2 H 2 O ( s )+4 HAc ( l ) have been studied. The molar dissolution enthalpies of the reactants and products in a certain solvent (3 M l −1 HNO 3 ) of this three reaction have been measured using an isoperibol calorimeter at 298 K. From these values, combined with auxiliary values, the standard molar formation enthalpies of Zn 2 HIO 6 ·1.25H 2 O (s), (298.2 K), Cd 2 HIO 6 ·1.25 H 2 O (s), (298.2 K) and Cu 2 HIO 6 ·2H 2 O (s), (298.2 K) have been determined to be Δ f H m θ (Zn 2 HIO 6 ·1.25 H 2 O (s), 298.2 K) = −1342.11 kJ mol −1 , Δ f H m θ (Cd 2 HIO 6 ·1.25H 2 O (s), 298.2 K) = −1405.49 kJ mol −1 and Δ f H m θ (Cu 2 HIO 6 ·2H 2 O (s), 298.2 K) = −1226.08 kJ mol −1 ." @default.
- W2024632595 created "2016-06-24" @default.
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- W2024632595 date "2000-06-01" @default.
- W2024632595 modified "2023-09-27" @default.
- W2024632595 title "A thermochemical study of hexaoxoiodata(VII) hydrates of the type M2HIO6·nH2O, where M=Cd, Cu, Zn" @default.
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- W2024632595 doi "https://doi.org/10.1016/s0040-6031(00)00417-2" @default.
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