Matches in SemOpenAlex for { <https://semopenalex.org/work/W2024643141> ?p ?o ?g. }
Showing items 1 to 84 of
84
with 100 items per page.
- W2024643141 abstract "Estrogens, a potent group of endocrine disruptors toward aquatic species, are primarily excreted as conjugates from humans and animals. Radioassay-based approaches with detailed speciation have been frequently conducted for environmental-fate studies for pesticides; however, such techniques have not been exploited for reproductive hormones, and especially for hormone conjugates. This article describes a simple, robust, and high-mass-recovery approach to investigate the fate and transformation of a prototype estrogen conjugate, that is, 17β-estradiol-3-glucuronide (E2-3G), and its metabolites (free estrogens) in a laboratory soil and water matrix without the need for enzymatic cleavage and/or fluorescent derivatization. E2-3G and its metabolites were baseline resolved in a single run using high-performance liquid chromatography (HPLC) and quantified by liquid scintillation counting of the HPLC effluents. Transformation of E2-3G and the disposition of its metabolites--the free estrogens 17β-estradiol and estrone--into aqueous, sorbed, and gaseous phases, were adequately accounted for in a soil-water batch system. High mass balances ranging from 99.0% to 114.1% were obtained. Although the method gave lower sensitivity (parts per billion) than tandem mass spectrometer (parts per trillion), it offered sufficient chromatographic resolution and sensitivity to study the fate of labile estrogens in environmental matrices, using the concentration range of this study. An additional advantage of the approach was the relatively low cost of the instrumentation employed. The presented approach can be successfully applied to study the fate of conjugated hormones and their metabolites in the environment allowing simultaneous discernment of complex fate and transformation processes in soil, water, and gas." @default.
- W2024643141 created "2016-06-24" @default.
- W2024643141 creator A5028708445 @default.
- W2024643141 creator A5035582035 @default.
- W2024643141 creator A5053449057 @default.
- W2024643141 creator A5075157118 @default.
- W2024643141 date "2013-02-01" @default.
- W2024643141 modified "2023-09-26" @default.
- W2024643141 title "Radioassay-Based Approach to Investigate Fate and Transformation of Conjugated and Free Estrogens in an Agricultural Soil" @default.
- W2024643141 cites W1966484089 @default.
- W2024643141 cites W1967457745 @default.
- W2024643141 cites W1968452316 @default.
- W2024643141 cites W1974066056 @default.
- W2024643141 cites W1975754873 @default.
- W2024643141 cites W1983552844 @default.
- W2024643141 cites W1988757070 @default.
- W2024643141 cites W1992806999 @default.
- W2024643141 cites W2016254390 @default.
- W2024643141 cites W2018616958 @default.
- W2024643141 cites W2037766564 @default.
- W2024643141 cites W2040956167 @default.
- W2024643141 cites W2053553993 @default.
- W2024643141 cites W2058989295 @default.
- W2024643141 cites W2063503858 @default.
- W2024643141 cites W2066583859 @default.
- W2024643141 cites W2069979194 @default.
- W2024643141 cites W2070968587 @default.
- W2024643141 cites W2076041955 @default.
- W2024643141 cites W2076109948 @default.
- W2024643141 cites W2080740648 @default.
- W2024643141 cites W2086010523 @default.
- W2024643141 cites W2094965981 @default.
- W2024643141 cites W2099926815 @default.
- W2024643141 cites W2101586155 @default.
- W2024643141 cites W2107273338 @default.
- W2024643141 cites W2115187178 @default.
- W2024643141 cites W2121178270 @default.
- W2024643141 cites W2144953998 @default.
- W2024643141 doi "https://doi.org/10.1089/ees.2012.0206" @default.
- W2024643141 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/3576898" @default.
- W2024643141 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23443733" @default.
- W2024643141 hasPublicationYear "2013" @default.
- W2024643141 type Work @default.
- W2024643141 sameAs 2024643141 @default.
- W2024643141 citedByCount "4" @default.
- W2024643141 countsByYear W20246431412013 @default.
- W2024643141 countsByYear W20246431412014 @default.
- W2024643141 countsByYear W20246431412015 @default.
- W2024643141 countsByYear W20246431412019 @default.
- W2024643141 crossrefType "journal-article" @default.
- W2024643141 hasAuthorship W2024643141A5028708445 @default.
- W2024643141 hasAuthorship W2024643141A5035582035 @default.
- W2024643141 hasAuthorship W2024643141A5053449057 @default.
- W2024643141 hasAuthorship W2024643141A5075157118 @default.
- W2024643141 hasBestOaLocation W20246431412 @default.
- W2024643141 hasConcept C107872376 @default.
- W2024643141 hasConcept C179998833 @default.
- W2024643141 hasConcept C185592680 @default.
- W2024643141 hasConcept C2776923573 @default.
- W2024643141 hasConcept C2778656385 @default.
- W2024643141 hasConcept C43617362 @default.
- W2024643141 hasConcept C55493867 @default.
- W2024643141 hasConcept C71315377 @default.
- W2024643141 hasConceptScore W2024643141C107872376 @default.
- W2024643141 hasConceptScore W2024643141C179998833 @default.
- W2024643141 hasConceptScore W2024643141C185592680 @default.
- W2024643141 hasConceptScore W2024643141C2776923573 @default.
- W2024643141 hasConceptScore W2024643141C2778656385 @default.
- W2024643141 hasConceptScore W2024643141C43617362 @default.
- W2024643141 hasConceptScore W2024643141C55493867 @default.
- W2024643141 hasConceptScore W2024643141C71315377 @default.
- W2024643141 hasLocation W20246431411 @default.
- W2024643141 hasLocation W20246431412 @default.
- W2024643141 hasLocation W20246431413 @default.
- W2024643141 hasLocation W20246431414 @default.
- W2024643141 hasOpenAccess W2024643141 @default.
- W2024643141 hasPrimaryLocation W20246431411 @default.
- W2024643141 hasRelatedWork W1976102031 @default.
- W2024643141 hasRelatedWork W2804760708 @default.
- W2024643141 hasRelatedWork W777961269 @default.
- W2024643141 isParatext "false" @default.
- W2024643141 isRetracted "false" @default.
- W2024643141 magId "2024643141" @default.
- W2024643141 workType "article" @default.