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- W2024643906 abstract "The novel phosphido complexes [thf(ArO)3WPM(CO)5] (3 a,b; Ar=2,6-Me2C6H3; M=W, Cr; 3 a is depicted here) can be prepared in high yields by the reaction of [W2(OAr)6] with tBuCP in the presence of [M(CO)5thf]. Initial reactivity studies with [(ArO)4W=O] and [(Ph3P)2Pt(2-C2H4)] resulted in the formation of dinuclear four-membered ring complexes and indicated the high side-on reactivity of these compounds. Theoretical studies of the model complexes [(HO)3WP], [(HO)3WPW(CO)5], and [thf(HO)3WPW(CO)5] give insights into the bonding situation." @default.
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- W2024643906 date "1999-09-24" @default.
- W2024643906 modified "2023-10-10" @default.
- W2024643906 title "Novel Complexes with a Short Tungsten–Phosphorus Triple Bond" @default.
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- W2024643906 doi "https://doi.org/10.1002/(sici)1521-3765(19991001)5:10<2890::aid-chem2890>3.0.co;2-#" @default.
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