Matches in SemOpenAlex for { <https://semopenalex.org/work/W2024646155> ?p ?o ?g. }
Showing items 1 to 100 of
100
with 100 items per page.
- W2024646155 endingPage "273" @default.
- W2024646155 startingPage "257" @default.
- W2024646155 abstract "An extensive study of the microwave spectrum of cyanamide has been undertaken, the analysis being based in part on semirigidbender calculations by the methods of Bunker and Szalay. Inversion lines of NH2CN, K−1 = 2 aQ branches and a number of vibrational satellites of the J = 2−1 transition were observed. A two-vibrational-state Hamiltonian was used to fit simultaneously the 0+ and 0− microwave data and yielded rotational constants X, Y, Z, DJ, DJK, d1, HJK as well as the inversion splitting and the μyz-connecting matrix element. Vibrational satellite data of seven isotopic species and infrared frequencies of NH2CN were included in the semirigid bender calculations: The NCN spine is nonlinear by ca. 5° in the equilibrium structure of the molecule. Also, rNHÅ = 0.9994 + 0.0144ϱ2; <HNH/2 = 60.39° − 0.1134ϱ2; rNCÅ = 1.3301 + 0.0327ϱ2 (ϱ is the inversion angle in rad); rCN = 1.1645 Å fixed. The inclusion of the NC bond flexing was necessary in order to reproduce the observed vibrational satellite patterns of NH2CN, NHDCN, and ND2CN. The barrier to inversion of the amino group is 510 ± 6 cm−1 with minima at ±45.0 ±0.2°. The inversion dipole moment is 0.91 ± 0.02 Debye." @default.
- W2024646155 created "2016-06-24" @default.
- W2024646155 creator A5024414057 @default.
- W2024646155 creator A5069137151 @default.
- W2024646155 creator A5074625141 @default.
- W2024646155 date "1985-12-01" @default.
- W2024646155 modified "2023-09-26" @default.
- W2024646155 title "Microwave spectrum and structure of cyanamide: Semirigid bender treatment" @default.
- W2024646155 cites W1596477515 @default.
- W2024646155 cites W1966671496 @default.
- W2024646155 cites W1968650512 @default.
- W2024646155 cites W1974724128 @default.
- W2024646155 cites W1974850774 @default.
- W2024646155 cites W1989014228 @default.
- W2024646155 cites W1998631110 @default.
- W2024646155 cites W2012162379 @default.
- W2024646155 cites W2018439931 @default.
- W2024646155 cites W2030155509 @default.
- W2024646155 cites W2037391524 @default.
- W2024646155 cites W2048765804 @default.
- W2024646155 cites W2057280024 @default.
- W2024646155 cites W2061608374 @default.
- W2024646155 cites W2095011948 @default.
- W2024646155 cites W2095054478 @default.
- W2024646155 cites W3004613803 @default.
- W2024646155 doi "https://doi.org/10.1016/0022-2852(85)90223-1" @default.
- W2024646155 hasPublicationYear "1985" @default.
- W2024646155 type Work @default.
- W2024646155 sameAs 2024646155 @default.
- W2024646155 citedByCount "45" @default.
- W2024646155 countsByYear W20246461552013 @default.
- W2024646155 countsByYear W20246461552019 @default.
- W2024646155 countsByYear W20246461552021 @default.
- W2024646155 countsByYear W20246461552022 @default.
- W2024646155 countsByYear W20246461552023 @default.
- W2024646155 crossrefType "journal-article" @default.
- W2024646155 hasAuthorship W2024646155A5024414057 @default.
- W2024646155 hasAuthorship W2024646155A5069137151 @default.
- W2024646155 hasAuthorship W2024646155A5074625141 @default.
- W2024646155 hasConcept C109007969 @default.
- W2024646155 hasConcept C121332964 @default.
- W2024646155 hasConcept C126255220 @default.
- W2024646155 hasConcept C127313418 @default.
- W2024646155 hasConcept C130787639 @default.
- W2024646155 hasConcept C147597530 @default.
- W2024646155 hasConcept C151730666 @default.
- W2024646155 hasConcept C158355884 @default.
- W2024646155 hasConcept C173523689 @default.
- W2024646155 hasConcept C185592680 @default.
- W2024646155 hasConcept C1893757 @default.
- W2024646155 hasConcept C2779606280 @default.
- W2024646155 hasConcept C32909587 @default.
- W2024646155 hasConcept C33923547 @default.
- W2024646155 hasConcept C40899509 @default.
- W2024646155 hasConcept C44838205 @default.
- W2024646155 hasConcept C46141821 @default.
- W2024646155 hasConcept C55493867 @default.
- W2024646155 hasConcept C62520636 @default.
- W2024646155 hasConcept C72319582 @default.
- W2024646155 hasConceptScore W2024646155C109007969 @default.
- W2024646155 hasConceptScore W2024646155C121332964 @default.
- W2024646155 hasConceptScore W2024646155C126255220 @default.
- W2024646155 hasConceptScore W2024646155C127313418 @default.
- W2024646155 hasConceptScore W2024646155C130787639 @default.
- W2024646155 hasConceptScore W2024646155C147597530 @default.
- W2024646155 hasConceptScore W2024646155C151730666 @default.
- W2024646155 hasConceptScore W2024646155C158355884 @default.
- W2024646155 hasConceptScore W2024646155C173523689 @default.
- W2024646155 hasConceptScore W2024646155C185592680 @default.
- W2024646155 hasConceptScore W2024646155C1893757 @default.
- W2024646155 hasConceptScore W2024646155C2779606280 @default.
- W2024646155 hasConceptScore W2024646155C32909587 @default.
- W2024646155 hasConceptScore W2024646155C33923547 @default.
- W2024646155 hasConceptScore W2024646155C40899509 @default.
- W2024646155 hasConceptScore W2024646155C44838205 @default.
- W2024646155 hasConceptScore W2024646155C46141821 @default.
- W2024646155 hasConceptScore W2024646155C55493867 @default.
- W2024646155 hasConceptScore W2024646155C62520636 @default.
- W2024646155 hasConceptScore W2024646155C72319582 @default.
- W2024646155 hasIssue "2" @default.
- W2024646155 hasLocation W20246461551 @default.
- W2024646155 hasOpenAccess W2024646155 @default.
- W2024646155 hasPrimaryLocation W20246461551 @default.
- W2024646155 hasRelatedWork W1975800166 @default.
- W2024646155 hasRelatedWork W1995248569 @default.
- W2024646155 hasRelatedWork W1996024444 @default.
- W2024646155 hasRelatedWork W2033420960 @default.
- W2024646155 hasRelatedWork W2048532243 @default.
- W2024646155 hasRelatedWork W2064504010 @default.
- W2024646155 hasRelatedWork W2083373116 @default.
- W2024646155 hasRelatedWork W2137503715 @default.
- W2024646155 hasRelatedWork W2369043814 @default.
- W2024646155 hasRelatedWork W4297849618 @default.
- W2024646155 hasVolume "114" @default.
- W2024646155 isParatext "false" @default.
- W2024646155 isRetracted "false" @default.
- W2024646155 magId "2024646155" @default.
- W2024646155 workType "article" @default.