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• W2024654410 abstract "An experimental and theoretical study of the electronic structure and the X-ray Si K and Si L emission bands of 4:2-coordinated alpha -quartz and 6:3-coordinated stishovite is presented. The nature of atomic states participating in the X-ray valence band spectra is identified. In particular the long-standing controversy about the role of Si 3d-like states is analysed; evidently, Si 3d-like electrons essentially contribute to the intensity of Si L emission bands. The authors have calculated the total density of states, the local partial densities of states, the ratios of the s, p and d charge components inside silicon and oxygen sited spheres, and the Si K and Si L emission bands. There is good agreement between their measured and calculated spectra. Reasons are given why in contrast with the Si K emission bands the Si L emission bands are insensitive to the local crystal structure of alpha -quartz and stishovite." @default.
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• W2024654410 date "1993-02-15" @default.
• W2024654410 modified "2023-10-16" @default.
• W2024654410 title "Local s, p and d charge distributions and X-ray emission bands of SiO₂: alpha -quartz and stishovite" @default.
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• W2024654410 doi "https://doi.org/10.1088/0953-8984/5/7/013" @default.
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