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- W2024654411 abstract "It is shown that experimental oscillator strengths or Lande g values of a small number of energy levels may be used to obtain certain of the Slater-Condon parameters of l4l+1l' electron configurations which may be used to predict a large number of the other energy levels. The analysis uses deduced values of eigenvector expansion coefficients for LS-coupled basis functions to transform the diagonal energy level matrix into a numerical LS Hamiltonian matrix. Equating this with the analytical Hamiltonian leads to simultaneous equations in the configuration parameters. The method is tested in three Ar I 3p5nl configurations with satisfactory results. In the case of Ar I 3p54d it is found that the introduction of an additional empirical electrostatic parameter leads to a substantially improved energy level fit. This parameter effectively takes into account the LS dependence of 3F Slater integrals." @default.
- W2024654411 created "2016-06-24" @default.
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- W2024654411 date "1984-01-28" @default.
- W2024654411 modified "2023-09-25" @default.
- W2024654411 title "Determination of empirical configuration parameters from experimental data in l4l+1l' electron configurations: application to Ar I 3p54s, 3p54p and 3p53d" @default.
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- W2024654411 doi "https://doi.org/10.1088/0022-3700/17/2/004" @default.
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