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- W2024659505 abstract "The reduction of prochiral ketones has been performed by Cr(II) L-amino acid complexes in aqueous DMF solution under mild conditions in good yields and moderate (up to 58%) ee values. The dependence of the yield and enantioselectivity on various factors such as the structure of the ligand, pH and the solvent has also been investigated. A mechanism based on SET from the Cr(II) ion followed by protonation by water and the formation of an organochromium intermediate is also proposed." @default.
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- W2024659505 date "2004-06-01" @default.
- W2024659505 modified "2023-10-14" @default.
- W2024659505 title "Enantioselective reduction of prochiral ketones by chromium(II) amino acid complexes" @default.
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- W2024659505 doi "https://doi.org/10.1016/j.tetasy.2004.04.017" @default.
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