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- W2024668907 abstract "Diallyl brassylate (DAB), a new monomer, and diallyl azelate (DAA) were converted to new prepolymers for comparison with analogous commercial products from diallyl o-and m-phthalate (DAMP). Respective prepolymers from DAB and DAA had Mn 28,000 and 40,000 and contained approximately 0.8 free allyl moiety per repeating unit. Only the DAB prepolymer exhibited crystallinity at low temperatures as detected by differential scanning calorimetry and x-ray diffraction. Aliphatic prepolymers have greater heat stability than aromatic ones and evolve fewer calories per double bond during curing than reported for DAMP prepolymer. Low shrinkage (<1%) on curing and clear, hard end products indicate the potential of aliphatic prepolymers as thermosetting plastics. Their liquid state at room temperature should be advantageous in many applications." @default.
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- W2024668907 date "1974-02-01" @default.
- W2024668907 modified "2023-09-26" @default.
- W2024668907 title "Allylic prepolymers from brassylic and azelaic acids" @default.
- W2024668907 doi "https://doi.org/10.1002/app.1974.070180201" @default.
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