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- W2024678186 abstract "Continuous and homogeneous layers of boron carbides are deposited from BCl3CH4H2 mixtures using a stagnation flow technique in the temperature range 1400–2000 K. The influence of the experimental parameters on the interfacial conditions of deposition is deduced from a comparison of the theoretical deposition rates and the solid compositions (calculated from a mass transfer equilibrium model) with the experimental values. The composition and structural changes of boron carbides are studied with respect to these interfacial conditions, especially the temperature and the actual closeness of the state of the system to equilibrium. A distinction is made between the stable phases deposited close to equilibrium and some kinetically favoured forms. The process conditions necessary for the deposition of continuous homogeneous thick coatings of different structures are indicated." @default.
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- W2024678186 date "1981-11-01" @default.
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- W2024678186 title "Composition and structural changes of boron carbides deposited by chemical vapour deposition under various conditions of temperature and supersaturation" @default.
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- W2024678186 doi "https://doi.org/10.1016/0022-5088(81)90196-x" @default.
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