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- W2024684443 abstract "Highly polarized 4′5′-bis(methylthio), 4′,5′-ethylenedithio, and 4′,5′-ethylenedioxy-4,5-dithiocyanotetra-thiafulvalenes [BMT-TTF(SCN)2, EDT-TTF(SCN)2, and EDO-TTF(SCN)2] were synthesized in moderated yields from 2-cyanoethylthio-TTF derivatives. EDO-TTF(SCN)2 formed a CT complex with TCNQF4 due to its moderate electron donating ability. The packing structure of the CT complex obtained by X-ray analysis shows many intermolecular interactions through the S•••S, S•••N, C•••N, and N•••O contacts. The strong intermolecular interactions composed of the donor–donor, donor–acceptor, and acceptor–acceptor combinations enhance the dimensionality of the molecular network in the CT-complex." @default.
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- W2024684443 date "2009-06-29" @default.
- W2024684443 modified "2023-10-18" @default.
- W2024684443 title "Synthesis, properties, and CT complex formation of highly polarized thiocyanotetrathiafulvalenes" @default.
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- W2024684443 doi "https://doi.org/10.1080/17415990902870919" @default.
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