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- W2024686037 abstract "Abstract Measurements of chemically induced dynamic nuclear polarization (CIDNP) often yield valuable and otherwise unavailable information about the mechanisms of chemical reactions. The purposes of this article are to explain the fundamentals of this spectroscopic technique in elementary terms and to show what kind of information a chemist can get by using this method. After a description of a few introductory experiments, the radical‐pair mechanism is treated in detail. From an analysis of two simple systems, Kaptein's rules for CIDNP net and multiplet effects are derived. The advantages and limitations of CIDNP for the study of chemical reactions are discussed, and practical hints for CIDNP experiments are given." @default.
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- W2024686037 date "1995-01-01" @default.
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- W2024686037 title "An introduction to chemically induced dynamic nuclear polarization" @default.
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- W2024686037 doi "https://doi.org/10.1002/cmr.1820070105" @default.
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