Matches in SemOpenAlex for { <https://semopenalex.org/work/W2024688591> ?p ?o ?g. }
- W2024688591 endingPage "3256" @default.
- W2024688591 startingPage "3248" @default.
- W2024688591 abstract "Abstract Motivated by recent molecular dynamics simulation studies of miscible blends of dynamically disparate polymers, we have revisited the experimentally measured dielectric relaxation in a 50/50 blend of poly(isoprene) and poly(vinyl ethylene) (PI/PVE). In contrast to efforts to explain the dielectric loss in PI/PVE blends in terms of a distribution of local environments leading to a broad distribution of segmental relaxation times (the so-called concentration fluctuation model), our analysis indicates that there is no evidence for significant broadening of the relaxation processes in the component polymers upon blending. Rather, we find that the dielectric loss of the 50/50 PI/PVE blend can be represented as a sum of α- and β-relaxation processes for the component polymers represented with Havriliak–Negami functions whose shape and relaxation strength are consistent with those obtained for the pure PI and PVE melts. The α-relaxation process for the PVE component was found to be dramatically influenced by blending, moving to much higher frequency with moderate narrowing, while the α-relaxation process for the PI component shifted to somewhat lower frequency with slight broadening, consistent with our MD simulations of a model blend and 2D NMR measurements on PI/PVE blends. In contrast, the β-processes in the PVE and PI components were found to be essentially uninfluenced by blending, with the latter accounting for the significant high-frequency loss observed in the PI/PVE blend." @default.
- W2024688591 created "2016-06-24" @default.
- W2024688591 creator A5010180208 @default.
- W2024688591 creator A5028759819 @default.
- W2024688591 date "2006-12-01" @default.
- W2024688591 modified "2023-10-18" @default.
- W2024688591 title "Dynamics of a poly(isoprene)/poly(vinyl ethylene) blend revisited: Component polymer relaxation and blend behavior" @default.
- W2024688591 cites W1963807101 @default.
- W2024688591 cites W1970446128 @default.
- W2024688591 cites W1986835682 @default.
- W2024688591 cites W1988820258 @default.
- W2024688591 cites W1995548252 @default.
- W2024688591 cites W1999054168 @default.
- W2024688591 cites W1999306312 @default.
- W2024688591 cites W2010133741 @default.
- W2024688591 cites W2012291798 @default.
- W2024688591 cites W2018639028 @default.
- W2024688591 cites W2023806557 @default.
- W2024688591 cites W2029005697 @default.
- W2024688591 cites W2045226111 @default.
- W2024688591 cites W2051810093 @default.
- W2024688591 cites W2057009283 @default.
- W2024688591 cites W2060540469 @default.
- W2024688591 cites W2061590044 @default.
- W2024688591 cites W2072301376 @default.
- W2024688591 cites W2072622669 @default.
- W2024688591 cites W2079540121 @default.
- W2024688591 cites W2080184387 @default.
- W2024688591 cites W2082215463 @default.
- W2024688591 cites W2109743340 @default.
- W2024688591 doi "https://doi.org/10.1016/j.eurpolymj.2006.08.005" @default.
- W2024688591 hasPublicationYear "2006" @default.
- W2024688591 type Work @default.
- W2024688591 sameAs 2024688591 @default.
- W2024688591 citedByCount "10" @default.
- W2024688591 countsByYear W20246885912013 @default.
- W2024688591 countsByYear W20246885912017 @default.
- W2024688591 countsByYear W20246885912018 @default.
- W2024688591 crossrefType "journal-article" @default.
- W2024688591 hasAuthorship W2024688591A5010180208 @default.
- W2024688591 hasAuthorship W2024688591A5028759819 @default.
- W2024688591 hasConcept C110884469 @default.
- W2024688591 hasConcept C121332964 @default.
- W2024688591 hasConcept C126348684 @default.
- W2024688591 hasConcept C15744967 @default.
- W2024688591 hasConcept C15920480 @default.
- W2024688591 hasConcept C159985019 @default.
- W2024688591 hasConcept C161790260 @default.
- W2024688591 hasConcept C168167062 @default.
- W2024688591 hasConcept C178790620 @default.
- W2024688591 hasConcept C185592680 @default.
- W2024688591 hasConcept C187404810 @default.
- W2024688591 hasConcept C188027245 @default.
- W2024688591 hasConcept C192562407 @default.
- W2024688591 hasConcept C2776029896 @default.
- W2024688591 hasConcept C2778597550 @default.
- W2024688591 hasConcept C2780959689 @default.
- W2024688591 hasConcept C2992561413 @default.
- W2024688591 hasConcept C521977710 @default.
- W2024688591 hasConcept C77805123 @default.
- W2024688591 hasConcept C97355855 @default.
- W2024688591 hasConceptScore W2024688591C110884469 @default.
- W2024688591 hasConceptScore W2024688591C121332964 @default.
- W2024688591 hasConceptScore W2024688591C126348684 @default.
- W2024688591 hasConceptScore W2024688591C15744967 @default.
- W2024688591 hasConceptScore W2024688591C15920480 @default.
- W2024688591 hasConceptScore W2024688591C159985019 @default.
- W2024688591 hasConceptScore W2024688591C161790260 @default.
- W2024688591 hasConceptScore W2024688591C168167062 @default.
- W2024688591 hasConceptScore W2024688591C178790620 @default.
- W2024688591 hasConceptScore W2024688591C185592680 @default.
- W2024688591 hasConceptScore W2024688591C187404810 @default.
- W2024688591 hasConceptScore W2024688591C188027245 @default.
- W2024688591 hasConceptScore W2024688591C192562407 @default.
- W2024688591 hasConceptScore W2024688591C2776029896 @default.
- W2024688591 hasConceptScore W2024688591C2778597550 @default.
- W2024688591 hasConceptScore W2024688591C2780959689 @default.
- W2024688591 hasConceptScore W2024688591C2992561413 @default.
- W2024688591 hasConceptScore W2024688591C521977710 @default.
- W2024688591 hasConceptScore W2024688591C77805123 @default.
- W2024688591 hasConceptScore W2024688591C97355855 @default.
- W2024688591 hasIssue "12" @default.
- W2024688591 hasLocation W20246885911 @default.
- W2024688591 hasOpenAccess W2024688591 @default.
- W2024688591 hasPrimaryLocation W20246885911 @default.
- W2024688591 hasRelatedWork W128043505 @default.
- W2024688591 hasRelatedWork W1564088826 @default.
- W2024688591 hasRelatedWork W1593155092 @default.
- W2024688591 hasRelatedWork W1990426000 @default.
- W2024688591 hasRelatedWork W2016501391 @default.
- W2024688591 hasRelatedWork W2028028245 @default.
- W2024688591 hasRelatedWork W2037041909 @default.
- W2024688591 hasRelatedWork W2081528498 @default.
- W2024688591 hasRelatedWork W2112636684 @default.
- W2024688591 hasRelatedWork W67730972 @default.
- W2024688591 hasVolume "42" @default.
- W2024688591 isParatext "false" @default.
- W2024688591 isRetracted "false" @default.