Matches in SemOpenAlex for { <https://semopenalex.org/work/W2024691437> ?p ?o ?g. }
Showing items 1 to 58 of
58
with 100 items per page.
- W2024691437 endingPage "269" @default.
- W2024691437 startingPage "265" @default.
- W2024691437 abstract "Die UV-spektroskopisch bei 25°C in Cyclohexan bestimmten Elektronendonator-Akzeptor(EDA)-Komplexbildungs-konstanten Kx (bezogen auf Molenbrüche) betragen für Acrylnitril-Styrol 1,0, Methacrylnitril-Styrol 0,5, Acrylnitril-α-Methylstyrol 1,1 und Methacrylnitril-α-Methylstyrol 1,1. Die Komplexbidungsenthalpien nehmen in der angegebenen Reihe der Comonomersysteme ab; demnach beeinflussen sterische Effekte die Komplexstabilität. Die Beteiligung von EDA-Komplexen am Wachstumsschritt der Acrylnitril-Styrol-Copolymerisation in Substanz kann auf Basis der Komplexkonzentrationsverhältnisse in Betracht gezogen werden. The electron donor-acceptor (EDA) complex formation constant Kx (related to molar fractions) as determined by UV spectroscopy at 25°C in cyclohexane were found to be 1.0 with acrylonitrile-styrene, 0.5 with methacrylonitrile-styrene, 1.1 with acrylonitrile-α-methylstyrene and 1.1 with methacrylonitrile-α-methycrylonitrile-α-methylstyrene. The values of the enthalpy of complex formation decrease in the series of comonomer systems indicated, thus the stability of the complexes being affected by steric effects. Considerations on the participation of EDA complexes in the propagation step of the acrylonitrile-styrene bulk copolymerization can be based on the concentration ratios of the complexes." @default.
- W2024691437 created "2016-06-24" @default.
- W2024691437 creator A5003124980 @default.
- W2024691437 creator A5057201191 @default.
- W2024691437 creator A5079960667 @default.
- W2024691437 date "1979-05-01" @default.
- W2024691437 modified "2023-09-27" @default.
- W2024691437 title "Einfluß von Molekülwechselwirkungen auf die radikalische Copolymerisation. III. UV-spektroskopische Bestimmung von EDA-Komplexbildungskonstanten in Comonomersystemen von Acrylnitril-Styrol Sowie deren α-Methylhomologen" @default.
- W2024691437 doi "https://doi.org/10.1002/actp.1979.010300509" @default.
- W2024691437 hasPublicationYear "1979" @default.
- W2024691437 type Work @default.
- W2024691437 sameAs 2024691437 @default.
- W2024691437 citedByCount "5" @default.
- W2024691437 crossrefType "journal-article" @default.
- W2024691437 hasAuthorship W2024691437A5003124980 @default.
- W2024691437 hasAuthorship W2024691437A5057201191 @default.
- W2024691437 hasAuthorship W2024691437A5079960667 @default.
- W2024691437 hasConcept C15920480 @default.
- W2024691437 hasConcept C178790620 @default.
- W2024691437 hasConcept C185592680 @default.
- W2024691437 hasConcept C188027245 @default.
- W2024691437 hasConcept C2777566558 @default.
- W2024691437 hasConcept C2778237882 @default.
- W2024691437 hasConcept C2778372188 @default.
- W2024691437 hasConcept C2780282147 @default.
- W2024691437 hasConcept C2780672802 @default.
- W2024691437 hasConcept C521977710 @default.
- W2024691437 hasConceptScore W2024691437C15920480 @default.
- W2024691437 hasConceptScore W2024691437C178790620 @default.
- W2024691437 hasConceptScore W2024691437C185592680 @default.
- W2024691437 hasConceptScore W2024691437C188027245 @default.
- W2024691437 hasConceptScore W2024691437C2777566558 @default.
- W2024691437 hasConceptScore W2024691437C2778237882 @default.
- W2024691437 hasConceptScore W2024691437C2778372188 @default.
- W2024691437 hasConceptScore W2024691437C2780282147 @default.
- W2024691437 hasConceptScore W2024691437C2780672802 @default.
- W2024691437 hasConceptScore W2024691437C521977710 @default.
- W2024691437 hasIssue "5" @default.
- W2024691437 hasLocation W20246914371 @default.
- W2024691437 hasOpenAccess W2024691437 @default.
- W2024691437 hasPrimaryLocation W20246914371 @default.
- W2024691437 hasRelatedWork W1917717498 @default.
- W2024691437 hasRelatedWork W1979857683 @default.
- W2024691437 hasRelatedWork W2010466759 @default.
- W2024691437 hasRelatedWork W2023943952 @default.
- W2024691437 hasRelatedWork W2024691437 @default.
- W2024691437 hasRelatedWork W2035228050 @default.
- W2024691437 hasRelatedWork W2049902526 @default.
- W2024691437 hasRelatedWork W2058066164 @default.
- W2024691437 hasRelatedWork W2090485141 @default.
- W2024691437 hasRelatedWork W2367133843 @default.
- W2024691437 hasVolume "30" @default.
- W2024691437 isParatext "false" @default.
- W2024691437 isRetracted "false" @default.
- W2024691437 magId "2024691437" @default.
- W2024691437 workType "article" @default.