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- W2024694666 abstract "The martensitic transformation in sodium is studied by means of a local pseudopotential theory. The total Helmholtz free energy is calculated as a function of temperature and crystal configuration for both the bcc and hcp phases of sodium. At $T=0$, the hcp phase is found to be stable, while the bcc phase is found to be stable at high temperatures. The inclusion of the zero-point energy at $T=0$ gives improved agreement with the experimentally determined energy differences between the bcc and hcp phases. It is found that the thermal expansion of the crystal does not play a significant role in the phase transition and the transition from hcp to bcc as the temperature increases can be explained by thermodynamic arguments." @default.
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- W2024694666 date "1971-02-15" @default.
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- W2024694666 title "Study of the Martensitic Phase Transition in Sodium" @default.
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- W2024694666 doi "https://doi.org/10.1103/physrevb.3.1234" @default.
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