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- W2024694966 abstract "The synthesis and structure of a five-coordinate Fe(II) complex, [FeIISMe2N4 (tren)](PF6) (1), which models the reactive properties of superoxide reductases (SORs), is reported. SORs catalyze the reduction of superoxide to peroxide in anaerobic organisms, thereby avoiding the O2 formed in the more typical superoxide degradation enzyme superoxide dismutase (SOD). The thiolate ligand contained in model 1, as well as in SORs, appears to play an important role in promoting SOR activity." @default.
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- W2024694966 date "2001-09-20" @default.
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- W2024694966 title "Modeling the Reactivity of Superoxide Reducing Metalloenzymes with a Nitrogen and Sulfur Coordinated Iron Complex" @default.
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- W2024694966 doi "https://doi.org/10.1021/ic010221l" @default.
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