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- W2024696054 abstract "Abstract Rate constants for the pyrolysis of 1-diazo-4,4-dimethyl-1,4-dihydronaphthalenes, 4a–4e, have been measured in methanol : 6% triethylamine. In contrast to non-rigid cases, like diphenyldiazomethanes, where all para substituents show a rate increase compared to hydrogen, these rates show a linear Hammett correlation for para substituents with σ+ = — 0.84. This observation is rationalized by a non-linear process for loss of nitrogen leading directly to the ground-state singlet of the carbene, 17. This carbene is then trapped to give the ether 11." @default.
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- W2024696054 date "1985-01-01" @default.
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- W2024696054 title "Substituent effects on the rate of carbene formation by the pyrolysis of rigid aryl substituted diazomethanes" @default.
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- W2024696054 doi "https://doi.org/10.1016/s0040-4020(01)96390-2" @default.
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