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• W2024697773 abstract "Abstract The synthesis and characterization of complexes of uranyl nitrate with methyl-pyridine-N-oxide isomers (picoline-N-oxide (2-picNO), 3-picoline-N-oxide (3-picNO) and 4-picoline-N-oxide (4-picNO)) as ligands (L) are described. They were prepared by reaction of hydrated uranyl nitrate with ligands in ethanolic solution (molar ratio 1:2). The compounds were characterized by CHN microanalytical procedures, infrared spectroscopy, X-ray powder diffraction, and TG/DTG. The analytical results suggest the general formula UO 2 (NO 3 ) 2 ·2L and the TG/DTG curves show similarities in the thermal behavior. The IR spectra data indicate that the ligands are coordinated to UO 2 2+ through the NO group oxygen. X-ray powder diffraction patterns do not indicate the presence of isomorphism for this series of compounds. The thermal decomposition of the complexes yield a mixture of UO 3 and U 3 O 8 as final product." @default.
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• W2024697773 date "2004-07-01" @default.
• W2024697773 modified "2023-09-27" @default.
• W2024697773 title "Preparation and characterization of uranyl complexes with three isomeric methyl-pyridine-N-oxide ligands" @default.
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• W2024697773 doi "https://doi.org/10.1016/j.jallcom.2003.11.118" @default.
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