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- W2024700695 abstract "High purity samples of a [Ag(pyrazine)2]S2O8 complex were obtained using modified synthetic pathways. Di(pyrazine)silver(II) peroxydisulfate is sensitive to moisture forming [Ag(pyrazine)2](S2O8)(H2O) hydrate which degrades over time yielding HSO4− derivatives and releasing oxygen. One polymorphic form of pyrazinium hydrogensulfate, β–(pyrazineH+)(HSO4−), is found among the products of chemical decomposition together with unique [Ag(I)(pyrazine)]5(H2O)2(HSO4)2[H(SO4)2]. Chemical degradation of [Ag(pyrazine)2]S2O8 in the presence of trace amounts of moisture can explain the very low yield of wet synthesis (11–15%). Attempts have failed to obtain a mixed valence Ag(II)/Ag(I) pyrazine complex via partial chemical reduction of the [Ag(pyrazine)2]S2O8 precursor with a variety of inorganic and organic reducing agents, or via controlled thermal decomposition. Thermal degradation of [Ag(pyrazine)2]S2O8 containing occluded water proceeds at T > 90 °C via evolution of O2; simultaneous release of pyrazine and SO3 is observed during the next stages of thermal decomposition (120–285 °C), while Ag2SO4 and Ag are obtained upon heating to 400–450 °C." @default.
- W2024700695 created "2016-06-24" @default.
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- W2024700695 date "2012-01-01" @default.
- W2024700695 modified "2023-10-12" @default.
- W2024700695 title "Thermal and chemical decomposition of di(pyrazine)silver(ii) peroxydisulfate and unusual crystal structure of a Ag(i) by-product" @default.
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- W2024700695 doi "https://doi.org/10.1039/c1dt10744e" @default.
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