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• W2024706209 abstract "Abstract The treatment of [Ru 3 (CO) 12 ] with 6,6′‐dimethyl‐2,2′‐bipyridine (Me 2 bipy) or 2,9‐dimethyl‐1,10‐phenanthroline (Me 2 phen) in THF at reflux temperature gives the trinuclear dihydride complexes [Ru 3 (μ‐H) 2 (μ 3 ‐L 1 )(CO) 8 ] (L 1 =HCbipyMe 1 a , HCphenMe 1 b ), which result from the activation of two CH bonds of a methyl group. The hexa‐, hepta‐, and pentanuclear derivatives [Ru 6 (μ 3 ‐H)(μ 5 ‐L 2 )(μ‐CO) 3 (CO) 13 ] (L 2 =CbipyMe 2 a , CphenMe 2 b ), [Ru 7 (μ 3 ‐H)(μ 5 ‐L 2 )(μ‐CO) 2 (CO) 16 ] (L 2 =CbipyMe 3 a , CphenMe 3 b ), and [Ru 5 (μ‐H)(μ 5 ‐C)(μ‐L 3 )(CO) 13 ] (L 3 =bipyMe 4 a , phenMe 4 b ) can also be obtained by treating 1 a and 1 b with [Ru 3 (CO) 12 ]. Compounds 2 a and 2 b have a basal edge‐bridged square‐pyramidal metallic skeleton with a carbyne‐type C atom capping the four Ru atoms of the pyramid base. The structures of 3 a and 3 b are similar to those of 2 a and 2 b , respectively, but an additional Ru atom now caps a triangular face of the square‐pyramidal fragment of the metallic skeleton. The most interesting feature of 2 a , 2 b , 3 a , and 3 b is that their carbyne‐type C atoms were originally bound to three hydrogen atoms in Me 2 bipy or Me 2 phen and, therefore, they arise from the unprecedented activation of all three CH bonds of C‐bound methyl groups. The pentanuclear compounds 4 a and 4 b contain a carbide ligand surrounded by five Ru atoms in a distorted trigonal‐bipyramidal environment. They are the products of a series of processes that includes the activation of all bonds (three CH and one CC) of organic methyl groups, and are the first examples of complexes having carbide ligands that arise from C‐bonded methyl groups. The alkenyl derivatives [Ru 5 (μ 5 ‐C)(μ‐ p ‐MeC 6 H 4 CHCHphenMe)(CO) 13 ] ( 5 b ), [Ru 5 (μ‐H)(μ 5 ‐C)(μ‐ p ‐MeC 6 H 4 CHCHphenMe)( p ‐tolC 2 )(CO) 12 ] ( 6 b ), and [Ru 5 (μ‐H)(μ 5 ‐C)(μ‐PhCHCHphenMe)(PhC 2 )(CO) 12 ] ( 7 b ) have been obtained by treating 4 b with p ‐tolyl‐ and phenylacetylene, respectively. Their heterocyclic ligands contain an alkenyl fragment in the position that was originally occupied by a methyl group. Therefore, these complexes are the result of the formal substitution of an alkenyl group for a methyl group of 2,9‐dimethyl‐1,10‐ phenanthroline." @default.
• W2024706209 created "2016-06-24" @default.
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• W2024706209 date "2006-01-23" @default.
• W2024706209 modified "2023-10-18" @default.
• W2024706209 title "Ruthenium-Cluster-Mediated Activation of All Bonds of a Methyl Group of 6,6′-Dimethyl-2,2′-bipyridine and 2,9-Dimethyl-1,10-phenanthroline: Transformation of the Latter into a 2-Alkenyl-9-methyl-1,10-phenanthroline Ligand" @default.
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• W2024706209 doi "https://doi.org/10.1002/chem.200500813" @default.
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