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• W2024709882 abstract "Transport properties of different liquids inducing crystallization in syndiotactic polystyrene (sPS) were investigated at 25°C. The weight uptake kinetics in the different liquids imply Fickian behaviour, with the exclusion of n-hexane and cyclohexane for which the weight uptake starts after an induction time. The equilibrium concentration of the different liquids in sPS is a function of the solubility parameter and shows a maximum with respect to chloroform, indicating a maximum in the polymer-solvent interaction. The swollen samples are birefringent but appear substantially amorphous on the basis of the X-ray diffractograms. After drying a well developed crystalline order appears, and the diffractograms indicate the presence of solvated structures, characterized by chains in helical conformation." @default.
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• W2024709882 date "1991-01-01" @default.
• W2024709882 modified "2023-10-14" @default.
• W2024709882 title "Solvent-induced crystallization of syndiotactic polystyrene in different liquids—sorption and diffusion phenomena" @default.
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• W2024709882 doi "https://doi.org/10.1016/0032-3861(91)90541-p" @default.
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